Reactions of Mononuclear and Dinuclear Metal-Alkylidyne Complexes with Phosphaalkynes: C≡PP and C≡Mo Metathesis
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Hill, Anthony F.
Howard, Judith A.K.
Spaniol, Thomas P.
Stone, F. Gordon A.
Szameitat, Jürgen
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The isolobal analogy between the fragments CR, P, and d5‐ML5 suggested the reaction of tBuC≡P with the Mo complex 1. Indeed, this reaction gave the metathesis product 2. The W complex 3 reacted with tBuC≡P to give an adduct 4, which can be regarded as an Fe(CO)3‐stabilized 1‐phospha‐3‐tungstacyclobutadiene.
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Angewandte Chemie International Edition in English
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