The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]

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dc.contributor.authorHill, Anthony F.en
dc.contributor.authorClark, George R.en
dc.contributor.authorRickard, Clifton E.F.en
dc.contributor.authorRoper, Warren R.en
dc.contributor.authorHerberhold, Maxen
dc.date.accessioned2026-01-02T10:41:25Z
dc.date.available2026-01-02T10:41:25Z
dc.date.issued1991-01-15en
dc.description.abstractThe crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η2-NS), with the pyramidal sulphur trans to chloride.en
dc.description.statusPeer-revieweden
dc.format.extent6en
dc.identifier.issn0022-328Xen
dc.identifier.otherWOS:A1991EX16300012en
dc.identifier.otherORCID:/0000-0003-2167-0604/work/181882300en
dc.identifier.scopus0001582445en
dc.identifier.urihttps://hdl.handle.net/1885/733802668
dc.language.isoenen
dc.sourceJournal of Organometallic Chemistryen
dc.subjectDouble-bond systemsen
dc.subjectMolecular-structureen
dc.subjectN-sulfinylanilineen
dc.subjectComplexesen
dc.subjectLigandsen
dc.titleThe coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]en
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage362en
local.bibliographicCitation.startpage357en
local.contributor.affiliationHill, Anthony F.; University of Warwicken
local.contributor.affiliationClark, George R.; The University of Aucklanden
local.contributor.affiliationRickard, Clifton E.F.; The University of Aucklanden
local.contributor.affiliationRoper, Warren R.; The University of Aucklanden
local.contributor.affiliationHerberhold, Max; University of Bayreuthen
local.identifier.citationvolume401en
local.identifier.doi10.1016/0022-328X(91)86232-Fen
local.identifier.pureea7a06a0-db98-4364-9cd1-fd1553c696f9en
local.identifier.urlhttps://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1991EX16300012&DestLinkType=FullRecord&DestApp=WOS_CPLen
local.identifier.urlhttps://www.scopus.com/pages/publications/0001582445en
local.type.statusPublisheden

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