The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]
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Hill, Anthony F.
Clark, George R.
Rickard, Clifton E.F.
Roper, Warren R.
Herberhold, Max
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The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η2-NS), with the pyramidal sulphur trans to chloride.
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Journal of Organometallic Chemistry
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