Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

dc.contributor.authorCook, Darren J.en
dc.contributor.authorHarlow, Karsten J.en
dc.contributor.authorHill, Anthony F.en
dc.contributor.authorWelton, Tomen
dc.contributor.authorWhite, Andrew J.P. en
dc.contributor.authorWilliams, David J.en
dc.date.accessioned2026-01-01T18:41:41Z
dc.date.available2026-01-01T18:41:41Z
dc.date.issued1998en
dc.description.abstractThe reaction of [Ru(=CC6H4OMe-4)Cl(CO)(PPh3)(2)] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{kappa(2)-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2(=CHR)(CO)(PPh3)(2)](M = Ru or Os; R = Ph or C6H4OMe-4) and [OsCl(=CHR)(OH2)(CO)(PPh3)(2)]ClO4.en
dc.description.statusPeer-revieweden
dc.format.extent3en
dc.identifier.issn1144-0546en
dc.identifier.otherWOS:000073569700002en
dc.identifier.otherORCID:/0000-0003-2167-0604/work/181882268en
dc.identifier.scopus0345983692en
dc.identifier.urihttps://hdl.handle.net/1885/733802007
dc.language.isoenen
dc.sourceNew Journal of Chemistryen
dc.subjectComplexesen
dc.subjectRuthenium(ii)en
dc.subjectMethyleneen
dc.subjectCarbonylen
dc.titleAlkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]en
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpage314en
local.bibliographicCitation.startpage311en
local.contributor.affiliationCook, Darren J.; Imperial College Londonen
local.contributor.affiliationHarlow, Karsten J.; Imperial College Londonen
local.contributor.affiliationHill, Anthony F.; Imperial College Londonen
local.contributor.affiliationWelton, Tom; Imperial College Londonen
local.contributor.affiliationWhite, Andrew J.P. ; Imperial College Londonen
local.contributor.affiliationWilliams, David J.; Imperial College Londonen
local.identifier.citationvolume22en
local.identifier.doi10.1039/a801542ben
local.identifier.purec338643b-8402-4b13-b520-d1d870a86e6cen
local.identifier.urlhttps://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:000073569700002&DestLinkType=FullRecord&DestApp=WOS_CPLen
local.identifier.urlhttps://www.scopus.com/pages/publications/0345983692en
local.type.statusPublisheden

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