Ruthenium clusters with nitrogen ligands IV. Double CH activation of ketimine methyl groups on triruthenium carbonyl clusters. Crystal structure of Ru<sub>3</sub>(μ-H)<sub>2</sub>[μ<sub>3</sub>-ν<sup>2</sup>-(N,C)-4-HOC<sub>6</sub>H<sub>4</sub>NCMeCH](CO)<sub>9</sub>. Et<sub>2</sub>0
Loading...
Date
Authors
Cifuentes, Marie P.
Jeynes, Tyrone P.
Gray, Matthew
Humphrey, Mark G.
Skelton, Brian W.
White, Allan H.
Journal Title
Journal ISSN
Volume Title
Publisher
Access Statement
Abstract
The reaction of Ru3(CO)12 with the Schiff base 4-hydroxyphenyl-N,N-dimethylimide in refluxing cyclohexane gave the title complex in excellent yield. An X-ray crystallographic study showed that the product is derived from an unusual double CH activation of the methyl group. An analogous reaction with the asymmetric Schiff base p-hydroxyphenyl-N,N-isobutylmethylimide showed that this reaction is specific for the imine-bound methyl group.
Description
Keywords
Citation
Collections
Source
Journal of Organometallic Chemistry
Type
Book Title
Entity type
Publication