Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes
| dc.contributor.author | Mason, Kevin | en |
| dc.contributor.author | Harnden, Alice C. | en |
| dc.contributor.author | Patrick, Connor W. | en |
| dc.contributor.author | Poh, Adeline W. J. | en |
| dc.contributor.author | Batsanov, Andrei S. | en |
| dc.contributor.author | Suturina, Elizaveta A. | en |
| dc.contributor.author | Vonci, Michele | en |
| dc.contributor.author | McInnes, Eric J. L. | en |
| dc.contributor.author | Chilton, Nicholas F. | en |
| dc.contributor.author | Parker, David | en |
| dc.date.accessioned | 2026-01-01T10:40:51Z | |
| dc.date.available | 2026-01-01T10:40:51Z | |
| dc.date.issued | 2018-07-10 | en |
| dc.description.abstract | Crystallographic, emission and NMR studies of a series of C 3 -symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb( iii ) and Eu( iii ) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 4 | en |
| dc.identifier.issn | 1359-7345 | en |
| dc.identifier.other | Bibtex:mason_exquisite_2018 | en |
| dc.identifier.scopus | 85050768921 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733799663 | |
| dc.language.iso | en | en |
| dc.source | Chemical Communications | en |
| dc.title | Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 8489 | en |
| local.bibliographicCitation.startpage | 8486 | en |
| local.contributor.affiliation | Mason, Kevin; Durham University | en |
| local.contributor.affiliation | Harnden, Alice C.; Durham University | en |
| local.contributor.affiliation | Patrick, Connor W.; Durham University | en |
| local.contributor.affiliation | Poh, Adeline W. J.; Durham University | en |
| local.contributor.affiliation | Batsanov, Andrei S.; Durham University | en |
| local.contributor.affiliation | Suturina, Elizaveta A.; University of Southampton | en |
| local.contributor.affiliation | Vonci, Michele; University of Manchester | en |
| local.contributor.affiliation | McInnes, Eric J. L.; University of Manchester | en |
| local.contributor.affiliation | Chilton, Nicholas F.; Chemistry Research, Research School of Chemistry, ANU College of Science and Medicine, The Australian National University | en |
| local.contributor.affiliation | Parker, David; Durham University | en |
| local.identifier.citationvolume | 54 | en |
| local.identifier.doi | 10.1039/C8CC04995E | en |
| local.identifier.pure | feeb10e1-5ac9-4829-a067-d7fe4ec5c794 | en |
| local.identifier.url | https://www.scopus.com/pages/publications/85050768921 | en |
| local.type.status | Published | en |