Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co<sub>2</sub> (µ-?<sup>2</sup>-PhC<sub>2</sub>Fe(CO)<sub>2</sub>(n-C<sub>5</sub>H<sub>5</sub>)) (CO)<sub>6</sub>
| dc.contributor.author | Bruce, Michael I. | en |
| dc.contributor.author | Neil Duffy, D. | en |
| dc.contributor.author | Humphrey, Mark G. | en |
| dc.date.accessioned | 2026-01-07T10:40:33Z | |
| dc.date.available | 2026-01-07T10:40:33Z | |
| dc.date.issued | 1985 | en |
| dc.description.abstract | The reaction between Co2(CO)8 and Fe(C2Ph)(CO)2(?-C5H5) gave the title complex in 44% yield. The molecular structure was determined from a single-crystal X-ray diffraction study, and consists of the transition metal acetylide acting as a conventional µ-alkyne ligand to a Co2(CO)g unit. Crystals are monoclinic, space group P21/n, with a 11•610(8), b 14•657(4), c 12•526(6) Å, ß 90•30(5)°, and Z 4; 1683 independent data were refined to R 0•080, Rw 0•087. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 5 | en |
| dc.identifier.issn | 0004-9425 | en |
| dc.identifier.other | ORCID:/0000-0002-4433-6783/work/162949493 | en |
| dc.identifier.scopus | 84970543278 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733803909 | |
| dc.language.iso | en | en |
| dc.source | Australian Journal of Chemistry | en |
| dc.title | Reactions of Transition Metal s-Acetylides. V* Synthesis and X-Ray Structure of Co<sub>2</sub> (µ-?<sup>2</sup>-PhC<sub>2</sub>Fe(CO)<sub>2</sub>(n-C<sub>5</sub>H<sub>5</sub>)) (CO)<sub>6</sub> | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 163 | en |
| local.bibliographicCitation.startpage | 159 | en |
| local.contributor.affiliation | Bruce, Michael I.; University of Adelaide | en |
| local.contributor.affiliation | Neil Duffy, D.; University of Adelaide | en |
| local.contributor.affiliation | Humphrey, Mark G.; Jordan Laboratories | en |
| local.identifier.citationvolume | 39 | en |
| local.identifier.doi | 10.1071/CH9860159 | en |
| local.identifier.pure | f8394153-fd22-4eb1-80cf-fce986e62363 | en |
| local.identifier.url | https://www.scopus.com/pages/publications/84970543278 | en |
| local.type.status | Published | en |