Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule
Date
Authors
Leubner, Sebastian
Bengtsson, Viktor E.G.
Synnatschke, Kevin
Gosch, Jonas
Koch, Alexander
Reinsch, Helge
Xu, Hongyi
Backes, Claudia
Zou, Xiaodong
Stock, Norbert
Journal Title
Journal ISSN
Volume Title
Publisher
Access Statement
Abstract
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- A nd dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.
Description
Keywords
Citation
Collections
Source
Journal of the American Chemical Society
Type
Book Title
Entity type
Publication