Free and coordinated biarsolyls
| dc.contributor.author | Kirk, Ryan M. | |
| dc.contributor.author | Hill, Anthony F. | |
| dc.date.accessioned | 2024-11-29T04:40:35Z | |
| dc.date.available | 2024-11-29T04:40:35Z | |
| dc.date.issued | 2023-08 | |
| dc.description.abstract | A trace side product from the reaction of [Mo(AsC4Me4)(CO)3(η-C5H5)] with [Mn(THF)(CO)2(η5-C5H4Me)] was identified as the biarsolyl complex [Mn2{μ-(AsC4Me4)2}(CO)4(C5H4Me)2] on the basis of a strategic synthesis from [Mn(THF)(CO)2(η5-C5H4Me)] and the pre-formed and structurally characterised biarsolyl (AsC4Me4)2. Crystallographic and computational data for this first example of a biarsolyl complex and free biarsolyls are discussed in the context of those for free biarsolyls. | |
| dc.description.sponsorship | We gratefully acknowledge the Australian Research Council (DP200101222 and DP230199215) for funding. | |
| dc.format.mimetype | application/pdf | en_AU |
| dc.identifier.issn | 1477-9226 | |
| dc.identifier.uri | https://hdl.handle.net/1885/733725178 | |
| dc.language.iso | en_AU | en_AU |
| dc.provenance | https://openpolicyfinder.jisc.ac.uk/id/publication/18010..."The Accepted Version can be archived in an Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 29/11/2024). | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation | http://purl.org/au-research/grants/arc/DP200101222 | |
| dc.relation | http://purl.org/au-research/grants/arc/DP230100215 | |
| dc.rights | © The Royal Society of Chemistry 2023 | |
| dc.source | Dalton Transactions | |
| dc.title | Free and coordinated biarsolyls | |
| dc.type | Journal article | |
| dcterms.accessRights | Open Access | |
| dspace.entity.type | Publication | |
| local.bibliographicCitation.issue | 37 | |
| local.bibliographicCitation.lastpage | 13243 | |
| local.bibliographicCitation.startpage | 13235 | |
| local.contributor.affiliation | Hill, A., Research School of Chemistry, The Australian National University | |
| local.contributor.authoruid | u4030185 | |
| local.identifier.doi | 10.1039/D3DT02070C | |
| local.publisher.url | https://pubs.rsc.org/ | |
| local.type.status | Accepted Version |