Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates
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Seraya, Elaine
Slack, Eric
Ariafard, Alireza
Yates, Brian F.
Hyland, Christopher J.T.
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Cyclopropenylmethyl acetates have been shown to undergo rapid and stereoselective gold catalyzed rearrangement to Z-acetoxydienes in high yield. DFT calculations have shown that while several reaction pathways can be envisaged only a single, ring-opening one operates.
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Organic Letters
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