A three-component hydrogen bonded framework
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Muang-Non, Phonlakrit
Perry-Britton, Meabh K.S.
Macreadie, Lauren K.
White, Nicholas G.
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Abstract
A porous three-component hydrogen bonded framework, 1⋅biphen⋅TP, was prepared from a tetra-amidinium component (14+) and two different dianions, benzene-1,4-dicarboxylate (terephthalate, TP2−) and biphenyl-4,4′-dicarboxylate (biphen2−). Interestingly, when the framework was prepared in ethanol/water, 1⋅biphen⋅TP forms even when an excess of either dicarboxylate is present. However, when only water is used as solvent, only two-component frameworks are formed.
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Chemical Communications
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