High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru<sub>2</sub>(μ-H)(μ-NC<sub>5</sub>H<sub>4</sub>)<sub>2</sub>(CO)<sub>4</sub>(NC<sub>5</sub>H<sub>5</sub>)<sub>2</sub>][Ru<sub>10</sub>(μ-H)(μ<sub>6</sub>-C)(CO)<sub>24</sub>]
| dc.contributor.author | Cifuentes, Marie P. | en |
| dc.contributor.author | Humphrey, Mark G. | en |
| dc.contributor.author | Skelton, Brian W. | en |
| dc.contributor.author | White, Allan H. | en |
| dc.date.accessioned | 2026-01-07T10:40:36Z | |
| dc.date.available | 2026-01-07T10:40:36Z | |
| dc.date.issued | 1993 | en |
| dc.description.abstract | Pyrolysis of Ru3(μ-H)(μ-NC5H4)(CO)10 in chlorobenzene results in the formation of [Ru2(μ-H)(μ- NC5H4)2(CO)4(NC5H5)2][Ru10(μ-H)(μ6-C)(CO)24] in high yield; an X-ray structural study suggests that the hydrido ligand in the anion, previously believed to occupy an interstitial tetrahedral site, possibly bridges a metal–metal bond external to the cluster core. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 3 | en |
| dc.identifier.issn | 0276-7333 | en |
| dc.identifier.other | ORCID:/0000-0002-4433-6783/work/162949543 | en |
| dc.identifier.scopus | 0000501314 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733803912 | |
| dc.language.iso | en | en |
| dc.source | Organometallics | en |
| dc.title | High-Nuclearity Ruthenium Carbonyl Cluster Chemistry. Synthesis and X-ray Structure of [Ru<sub>2</sub>(μ-H)(μ-NC<sub>5</sub>H<sub>4</sub>)<sub>2</sub>(CO)<sub>4</sub>(NC<sub>5</sub>H<sub>5</sub>)<sub>2</sub>][Ru<sub>10</sub>(μ-H)(μ<sub>6</sub>-C)(CO)<sub>24</sub>] | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | 4274 | en |
| local.bibliographicCitation.startpage | 4272 | en |
| local.contributor.affiliation | Cifuentes, Marie P.; University of New England | en |
| local.contributor.affiliation | Humphrey, Mark G.; University of New England | en |
| local.contributor.affiliation | Skelton, Brian W.; University of Western Australia | en |
| local.contributor.affiliation | White, Allan H.; University of Western Australia | en |
| local.identifier.citationvolume | 12 | en |
| local.identifier.doi | 10.1021/om00035a006 | en |
| local.identifier.pure | bdf7452f-a1ce-4a10-b74b-9a09e656473d | en |
| local.identifier.url | https://www.scopus.com/pages/publications/0000501314 | en |
| local.type.status | Published | en |